Has a College Football game ever ended 33-4?
It has. 33-4 has been a College Football final 2 times in 84,334 games. The first was Williams beat Tufts on October 6, 1886; the latest was Harvard beat Bates on October 5, 1907.
That makes 33-4 the 1610th most common final score out of 2,215 that have ever occurred in College Football. One point away, 34-4 has happened 7 times and 33-5 has happened 4 times.